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Synthesis of Homo- and Heterocyclic Silanes Via Intermediates with Si=Si Bonds (Report)

Pure and Applied Chemistry 2010, March

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INTRODUCTION Stable disilenes, i.e., compounds with kinetically or thermodynamically stabilized Si=Si bonds [1], have been intensely studied since the isolation of the first example by West, Michl, and Fink in 1981 [2]. The development was driven by the fundamental interest in the Si=Si bond as well as its physical and chemical properties. As documented by X-ray diffraction studies, the Si=Si bond exhibits a high degree of conformational flexibility (Scheme 1) resulting in planar (I) [3], twisted (II) [4], trans-bent (III) [5], and slightly ds-bent conformations (IV) [6].

Synthesis of Homo- and Heterocyclic Silanes Via Intermediates with Si=Si Bonds (Report)
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  • Available on iPhone, iPad, iPod touch, and Mac.
  • Category: Chemistry
  • Published: 01 March 2010
  • Publisher: International Union of Pure and Applied Chemistry
  • Seller: The Gale Group, Inc.
  • Print Length: 14 Pages
  • Language: English
  • Requirements: To view this book, you must have an iOS device with iBooks 1.3.1 or later and iOS 4.3.3 or later, or a Mac with iBooks 1.0 or later and OS X 10.9 or later.

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